PokéBase - Pokémon Q&A
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Unfortunately, No. The reason is because Victini, Kubfu/Urshifu, Calyrex, Glastrier, and Spectrier, are shiny locked, resulting in not being able to get them as shinies. And with that logic, you cannot get a complete Shiny National Pokédex in Pokémon home.

Hope I helped!

edited by
not yet, anyways
Well yeah
Wait calyrex and glastrier can be shiny?
Oops, forgot those.
victini too, shiny locked
Oh! Right. Sorry, I haven’t played Black/White.
Ok thanks
No problem!