PokéBase - Pokémon Q&A
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If so, How?

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Yes, it is possible to trade between LeafGreen and Pokemon XD. You must have defeated Greevil in Pokemon XD to trade. You can only trade purified Pokemon. You cannot trade Shadow Pokemon, because the GBA games don't have the data for shadow moves.

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Ok, how do I link them together?
Look at this website and you'll find all you need to know.
http://wiki.answers.com/Q/How_do_I_transfer_Pokemon_from_XD_to_Pokemon_Leaf_Green
Lol you two xD
Screen shot :3
I agree with the last statement.