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With Seaking as the parent

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The compatible breeding partners with Goldeen that can teach it Psybeam through breeding would be Remoraid and Octillery, which both learn the move at level 22. Simply breed a female Seaking with a male Octillery/Remoraid with Psybeam, and you should get a Goldeen with the egg move you want.

Though, Remoraid must be traded over from Emerald, as they are unobtainable otherwise. Remoraid and Octillery can be caught in Emerald at the Safari Zone in the Southern Extension, both Remoraid and Octillery can be caught with the Super Rod already knowing Psybeam already, and Remoraid can also be caught there with the Good Rod.

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