If I had to guess, it's because Zamazenta has good defenses, but not much to take advantage of them. It doesn't have reliable recovery like Dusk Mane, doesn't have that great of a move pool, limiting it's options, and it's attacking stats are lacking compared to other things in AG. On the other hand Zacian is a force to be reckoned with. With Swords Dance at it's disposal, an ability that gives it a +1 Atk boost every time it switches in, and a Hero form that can run sets such as Choice Band, there's few things that can switch into Zacian safety, and even then, it has options to take care of most of them. As for why H-O-M-B is Ubers, I'm guessing it was too strong for OU. These are just guesses though, I don't know for certain.