PokéBase - Pokémon Q&A
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Chikorita, Tepig & Totodile

At the beginning: You pick one of them as you begin the game.

Wild Zone 20: In the post-game, Wild Zone 20 (in the middle of the city) unlocks. You can encounter all three Legends: Z-A starters from there.

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Bulbasaur, Charmander & Squirtle

Side Mission 022 (A Call from Mable): In this side mission, you pick one of the Kanto starters to keep. To unlock the mission, you need to defeat Rintaro in Main Mission 08. After healing in a Pokemon Centre, you'll receive the call from Mable to collect your starter.

Wild Zone 20: All three Kanto starters can also be encountered in Wild Zone 20, unlocked in the post-game.

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Chespin, Fennekin & Froakie

Side Mission 007 (A Feisty Chespin): Complete Main Mission 05. Then, go to Academie Etoile and talk to Axi, who is standing near a taxi. Defeat Chespin three times, and you'll be able to add it to your team.

Wild Zone 17: Complete Main Mission 24. This unlocks Wild Zone 17, where you can encounter wild Chespin.

Side Mission 008 (Get Well, Fennekin): Complete Main Mission 05. Then, go to Magenta District and talk to Branche, who is standing in the grass beside a building. Accept the mission, which involves you collecting a Revitalizing Twig to heal Fennekin. Bring it back to Branche to get Fennekin.

Wild Zone 18: Complete Main Mission 30. This unlocks Wild Zone 18, where you can encounter wild Fennekin.

Side Mission 009 (A Challenge from Froakie): Complete Main Mission 05. Then, go to Jaune Sector 8 and talk to Surv, who is standing under scaffolding nearby the Pokemon Centre. Accept the mission, which involves climbing three courses made of scaffolding under time pressure, before you're invited to take Froakie.

Wild Zone 16: Complete Main Mission 24. This unlocks Wild Zone 16, where you can encounter wild Froakie.

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Kanto Starters:

After achieving rank W, the next day you'll run an errand that ends with you battling one of your fellow members of Team MZ. After you battle her, heal your Pokémon at a Pokémon Center and you'll receive a call on your Rotom phone from Mable. The appropriately named side mission "A Call from Mable" will then become available. To complete it, all you have to do is head to the Pokémon Research Lab and go up to Mable's office where the Kanto starters will be waiting. Bulbasaur, Charmander, and Squirtle will be off to the side, and you're allowed to select one at this point in the game. Pick whichever one you want and they'll be added to your team. To get the remaining two Kanto starters, unfortunately you'll have to wait until Pokémon Legends: Z-A's post-game. You can also always ask a very generous friend to trade you their Kanto starter, but since there's no breeding in this game, that may be too heavy of an ask.

The Kanto starters will appear in wild zone 20 postgame.

Kalos Starters

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would be nice to have an overview of how to get the kalos starters. you don't need to give every detail, but linking to a website is pointless. it'd be better if you just said "you need to do x" without giving a full guide
Can you get the ZA starters that you didn't pick?
@Bird??? yeah

@HT sorry I didn't see this soon enough but Fizz made a better answer so don't really need to anymore