PokéBase - Pokémon Q&A
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It would not for Covert Cloak, as that prevents the stat drop.
However, it would for White Herb, as the herb just effectively gives a countering stat boost to the lowered one, and that means a stat would be dropped, activating Defiant.

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I answered first :(
they both say 7 hours ago :P
I answered then Ax109 answered better
jeez I just thought he explained it better thats all.
Yeah, I thought about commenting on Trapich's, but I felt it would be less hassle if I just put the answer I thought was correct, instead of having a lengthy comment conversation
To be fair, your answer is better than mine
1 vote

No
The Covert cloak prevents the stat drops and so defiant would not activate.
However the white herb would still activate defiant since it does not prevent the stat drop, it just cures it after

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