Like for example,Pinsir.it can only learn focus punch via Tm.....are there any pinsirs that learn focus punch in the anime?
There are too many to mention, from Pikachu's Iron-tail, to Darkrai's Ice-beam. If you want to know all of the moves Pokemon in Anime have ever known, go on Bulbapedia it has a complete list for each Pokemon you search. http://bulbapedia.bulbagarden.net/wiki/Ash's_Pikachu is an example. But remember, you must search the name of trainer and the Pokemon, like above (Ash's Pikachu).
SE on Sandile (B/W), T-Bolt on Linoone (Advanced Generation) to name a few. Shx, S-Toss isn't a TM. However, it's true that it can't learn it via Level-Up.