PokéBase - Pokémon Q&A
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I have a Totodile with it and I have seen others have it like Koffing so how do I give it to my Electrode, or can't it learn it? It is the IQ skill that shields a friend in the critical zone of HP.

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All Pokemon in the B, H, and E IQ groups can have Body Guard.

You can look up IQ Group Pokemon Here

I never even knew about IQ groups.
Neither did I before I looked it up for you XD