Meta Rate My Team PokéBase - Pokémon Q&A
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I know Protect and Toxic, but are there any others?

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  • Hidden Power
  • Double Team
  • Return
  • Frustration
  • Round
  • Swagger
  • Facade
  • Substitute

Protect cannot be learned by all Pokemon that can learn TMs - Regigigas can't.

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Not all pokemon can learn Substiute.
"What are all the TMs that every Pokemon can learn besides the Pokemon that can't learn any?"
Read the title, bud.