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And can you still Ev train when a Pokemons level is 100? And in some answers theres some Ev's like 252 Sp.attack/4 Speed/254 Defense but can you have 4 speed and 252 attack.

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Maybe with berries.

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Yes you can do it with the EV reducing berries.
>Pomeg Berry – Lowers a Pokémon's HP by 10 EVs.
Kelpsy Berry – Lowers a Pokémon's Attack by 10 EVs.
Qualot Berry – Lowers a Pokémon's Defense by 10 EVs.
Hondew Berry – Lowers a Pokémon's Special Attack by 10 EVs.
Grepa Berry – Lowers a Pokémon's Special Defense by 10 EVs.
Tamato Berry – Lowers a Pokémon's Speed by 10 EVs.

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