PokéBase - Pokémon Q&A
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HELLO I want to know if in black and white there its an easy mode to train Deino (monzou) to evolve, if you need here are Deino informations.

Deino - Dark/Dragon
Deino -> lvl 50 -> Zweilous -> lvl 64 -> Hydreigon

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As with all the games you just need to fight high level pokemon. If you have already beaten the Elite Four then you can battle them again, or use whatever the "Victory Road" equivalent is in B/W.