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Say its night and Im catching heatran who is in the stark Mt. Will dusk balls double catch rate add one?

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Yes they do. The catch rate rises to 3.5 if I did math right.

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Yor welcome
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No. The effect does not stack. However, the catch rate is still 3.5, whether you use it at night, cave, or both.

Source (Click on Dusk Ball)

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