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E.g. if Kyurem-B had Freeze Shock, and you then separates it to Kyurem and Zekrom, what would happen?

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Here is how it works. If the Kyurem B/W knows Freeze Shock/Burn, then after it separates the Kyurem will know Glaciate. If it knows Fusion Flare/Bolt, after separation it will know Scary Face.

Source: Tested it myself

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its not freeze burn, its ice burn