PokéBase - Pokémon Q&A
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Curious.

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You can get three:
-one in the battle company in castelia city from the janitor on the 1st floor right as you enter the battle company.
-from the Pokemon fan club chairman after you level up a Pokemon 25-49 levels.
-held by the shining Benga's dratini/gible after completing white tree hollow/black skyscraper.
You can get more through cheating or trading but thats all for ingame
Source: http://bulbapedia.bulbagarden.net/wiki/Exp_Share#Exp._Share

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