Meta Battle Subway PokeBase - Pokemon Q&A
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The final move Growlithe learns, Flare Blitz, is the best move for Arcanine. As such, you should evolve Growlithe at level 45. Crunch and Outrage are also somewhat useful niche moves. Usually you'll have other moves in place of them, but ingame they can be handy.

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Thanks!
Yeah,I sketched Flare Blitz from a Darmanitan with my smeargle,and now it kills!!