PokéBase - Pokémon Q&A
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HeartGold: Cianwood City (Rock Smash) and a person will give you one, Vermillion City (Rock Smash), Safari Zone (using objects.)

Diamond: Route 224 with the Emerald version inserted in the game cartridge slot.

Emerald: Altering Cave, Safari Zone (Rock Smash)

You can also always trade for it.

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