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One that can leaf Surf


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Well, your starter.

In any case, you get a Lapras in Silph Co., after defeating some Rockets. That's probably the earliest Surf user you can get apart from Squirtle.

Pokemon Leaf Green Walkthrough - Saffron City

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you can also get a vaporeon by using a water stone on the eevee you can get from the building in celadon city