PokéBase - Pokémon Q&A
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I'm not sure what you mean by appearing the second time, because it stays in the same spot until you catch it, where it then travels around with you. However, I am sure about where it is caught, and that would be in the middle of Route 22, you can't miss it.

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(Credit to Serebii for the picture)

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I guess the Q is referring to if you faint Terrakion; it reappears after you beat the E4 (and yea in the same place).