PokéBase - Pokémon Q&A
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I suggest you evolve it at lv.39. It learns Double Edge at that level and this is useful since Skitty>>>>>Delcatty have better offensive power then Sp. Offensive Power. After level 39 Skitty and Delcatty don't learn any other moves in generation III.
I still do recommend that you teach Skitty specially attacking moves since it doesn't have much acces to offensive moves.

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