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I'm making a team, but I need a Pokemon with a high Special Attack stat. I will prefer Pokemon that can catch in generation 5 or 4.

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Many Pokemon are tied, so they will all be listed. Many of these Pokemon were actually introduced in Gen 5 and 4, so they fit your requirements well.

  1. Chandelure (Base 145)
  2. Darmanitan-Zen Mode (Base 140)
  3. Alakazam, Porygon-Z and Volcarona (Base 135)
  4. Gengar, Espeon, Glaceon and Magnezone (Base 130)
  5. Exeggutor, Duosion, Reuniclus, Gardevoir, Roserade, Magmortar, Beheeyem and Hydreigon (Base 125)
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thanks :)
No problem :)
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Chandelure (145)
Darmanitan (Zen Mode) (140)
Alakazam (135)
Porygon-Z (135)
Volcarona (135)
Gengar (130)
Espeon (130)

Hope I helped. :)
Source: PokemonDB

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As Of Gen 8:
COUNTING MEGAS:
1. Mega Alakazam
2. Mega Gengar
3. Mega Gardevoir
4. Mega Ampharos
5. Mega Charizard Y
Not Counting Megas:
1. Ash Greninja
2. Cursola
3. Vikavolt
4. Chandelure
5. Volcorona

Hope this helped!

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Here is a list, up to date as of gen 9, excluding megas and legendary Pokemon, showing the top 5 Pokémon in Sp. Attack (excluding legendaries), with an option for Pokémon obtainable in BW/DPP:

1st:
- Overall: Xurkitree at 173
- Obtainable in gen 4/5: Chandelure at 145

2nd:
- Overall: Ash-Greninja at 153
- Obtainable in gen 4/5: Darmanitan (Zen Mode) at 140

3rd:
- Overall: Tied bewtween Cursola, Vikavolt, and Chandelure at 145
- Obtainable in gen 4/5: Volcarona at 135

4th:
- Overall: Tied between Iron Moth, Wishiwashi (School Form), Aegislash (Blade Form), and Darmanitan (Zen Mode) at 140
- Obtainable in gen 4/5: Tied Porygon-Z and Alakazam at 135

5th:
- Overall: Tied between Raging Bolt and Pheromosa at 137
- Obtainable in gen 4/5: Tied between Glaceon, Magnezone, Espeon, and Gengar at 130


Source: Pokédex with stats--Pokémon Database

Hope I helped!

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