PokéBase - Pokémon Q&A
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Checked the page and it says wild Pokémon. Just wondering if it works on gift Pokémon. I mean transferring the nature to the gift Pokémon.

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We've had a similar question to this before, but it was done injustice.
Anyways, the answer is no it will not work on Gift Pokemon.
You have stated that it only works on gift Pokemon, which is not an encounter in the wild.

>"From Pokémon Emerald onwards, if a Pokémon with this Ability is leading the party, there is a 50% chance that wild Pokémon encountered will have the same Nature as the Pokémon with Synchronize. This does not apply to roaming or gift Pokémon. In Emerald, it did not apply to stationary Pokémon either, such as Regirock or Rayquaza." - Bulbapedia

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Aww... Well good answer
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It works for all Pokemon, unless they are already statused :)
For the other Synchronize, no, it doesn't work.

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Hope I helped :3
I think she means the chance of getting pokemon of the same nature.
I really don't know xD
Yeah, I'm talking about getting the same nature, poorly explaining
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This might answer your question.

Hope I helped. :)
Source: Link shown above.

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