PokéBase - Pokémon Q&A
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Not particularly CATCH, Pokemon will just JOIN your team. And since you really are playing as a Pokemon in the game, it would seem awkward to catch Pokemon with a Pokeball. xD

Hope I helped. :)

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How do they join?
When you defeat a wild Pokemon, there's a chance that they will ask to join your team. You then get an option to accept or reject, along with an option to name them.
Does there, like, conscience come to life and ask you to join? o_o
^ I reread that about 4 times and still don't understand what you asked..