PokéBase - Pokémon Q&A
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In my white 2 I was catching bunch of Pokemon, they where all about level 40-50 and I only had to throw the pokeball once at full hp for all of them, but when I checked the pc their nature were all impish, so dose the nature of the Pokemon determine the catch rate?
The Pokemon the I caught were carvahna, clamperl, and finneon

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No, natures do not affect catch rate. Sorry.

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