PokéBase - Pokémon Q&A
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I haven't found it yet for some reason.

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In Anistar City's Pokemon Centre, there is a Hex Maniac (girl with purple hair) who will give you a different TM at certain times of the day. Flamethrower (TM35) is one of these. It is available from 11 a.m. until 5:59 p.m.

Be mindful that 3DS Pokemon games have a harsh timegate that freezes time-based events for 24-48 hours after you change the 3DS clock. The fastest way is to wait until it's 11 a.m. on your 3DS once again.

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It's in Anistar City

Cross the bridge. The Pokemon Center is waiting. Inside is a girl who will give you TM 35, Flamethrower. Oooo. (She gives you different TMs at different times of the day. I got Flamethrower at 5:47. I'll check back with her tomorrow.)

Some guy's walkthrough :P

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is this at AM or PM, you need to specify!
please try not to necro old threads. Also, the answer to that is 11:00 AM-5:59 PM.