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On X/Y!

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Here's an easy way for you:

  1. Breed a Male Espurr that knows Fake Out with a Female Sneasel/Weavile.
  2. Once bred, hatch the egg, and the new Sneasel should know Fake Out.

Espurr learns Fake Out at Level 19.

[Source][1]


You can also substitute Espurr with the following Pokemon if they are male and know Fake Out:

Meowth, Persian, Nuzleaf, Shiftry, Skitty, Delcatty, Glameow, Purugly, Purrloin, Liepard, Mienfoo, Mienshao, Meowstic (M or F), Pikachu, Raichu, Seel, Dewgong, Aipom, Delibird, Spinda, Kecleon, Chimchar, Monferno, Infernape, Ambipom, Buneary, Lopunny, Scraggy, Scrafty, Smeargle
[1]: http://www.serebii.net/pokedex-xy/egg/461.shtml#fakeout

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You can breed it with any of the following males that knows Fake Out already:
Meowth
Persian
Tyrogue
Lombre
Nuzleaf
Makuhita
Hariyama
Skitty
Delcatty
Sableye
Glameow
Purugly

Source

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