PokéBase - Pokémon Q&A
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No it does not, Sliggo can only evolve into Goodra by natural rain.

You pretty much have to look for rain on the routes as it constantly changes from route to route

Hope I helped :)

Source: experiance when I tried evolving mine

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No problem :D
well, you can change your 3DS time, but..
Try route 14
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No, it doesn't
For Sliggo to evolve you need to level it up in natural rain.

This means you can't evolve it by using Rain Dance.

This is both Source and tips and tricks on how to find natural rain (marriland forums)

Hope this helped!

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lol same thing