PokéBase - Pokémon Q&A
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Says it all

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These are all the qualities of the Ralts she trades you.

Yes, the Ralts you get will always have Synchronize according to Bulbapedia's Diantha Page.

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Yes, it will. It will also always be modest, as I have reset the game countless times and have always got a modest Ralts with sycronize on both my X and Y version.

source: Experience

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