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If my HA seviper uses toxic on a Pokemon with safe guard, will it work?

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Infiltrator

Infiltrator ignores the effects of Reflect, Light Screen and Safeguard. In other words, if the opponent has used Safeguard, Toxic would still badly poison them.

yes.


And Substitute since gen VI.
commented 12 seconds ago by The Noby

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And Substitute since gen VI.
Will it damage Pokemon with a Substitute without having to break the substitute first?  That would be awesome.
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It should because infiltrator ignores the effects of safeguard, quick guard and wide guard.

Infiltrator ignores the effects of Reflect, Light Screen and Safeguard. In other words, if the opponent has used Safeguard, Toxic would still badly poison them.

Source: The PokemonDatabase

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