Water Shuriken(greninja)
Mat Block(greninja)
Mystical Fire(Delphox)
Spiky Shield(chesnaught)
Crafty shield(klefki)
Sketch(smeargle)
Flying press(hawlucha)
Frenzy Plant(all grass starters)
Blast burn(all fire starters)
Hydro cannon(all water starters)
Payday(meowth)
Barrage(exeggcute line)
Softboiled(chansey line)
Conversion(porygon line)
Conversion 2(porygon line)
Octazooka(octillery)
Present(delibird)
Smellingsalts(makuhita line)
Defend order(vespiquen)
Attack order(vespiquen)
Heal order(vespiquen)
Chatter(chatot)
Heat crash(tepig line)
Secret power(audino)
Night daze(zorua line)
Kings shield(aegislash)
Tail slap(minccino line)
Electroweb(joltik line)
Gear grind(klink line)
Shift gear(klink line)
Head charge(bouffalant)
Fiery dance(Volcarona)
Powder(vivillon)
Noble roar(Litleo line)
Parting shot(pancham line)
Aromatic list(aromatisse)
Topsy turvy(inkay line)
Happy hour(inkay)
Electrify(helioptile line)
Forests curse(phantump line)
Trick-or-treat(gourgeist line)
And that's it so far. Hope I helped!
Source: http://bulbapedia.bulbagarden.net/wiki/Signature_moves#List_of_Pok.C3.A9mon_and_their_signature_moves
