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Since I do tend to Super Train often, and since I did go through the trouble of obtaining every single Power item, I want to know: Does having a Power item on a Pokemon affect its Super Training?

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Each Super Training balloon has a set number of EVs it gives that cannot be altered in any way, including with Pokerus, Power Items, etc.

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Is the only way to increase the earned evs is by traditional training?
You can Horde EV train.  http://www.smogon.com/forums/threads/a-guide-to-ev-training-with-hordes.3490052/
But you can't boost EV training at all if you do Super Training.