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You can get it in Sea Mauville or from a fan after participating in a Master Rank contest.

Hope I helped. :)
Source: http://www.serebii.net/itemdex/destinyknot.shtml

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I was 30 seconds too slow ;_;
and i was 5 minutes late XD
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In the Abandoned Ship/Sea Mauville, there's a couple. It's a random chance, but if you beat them, they'll give you a destiny knot.

You also have a random chance of getting one from a fan after you beat a Master Rank Contest.

Other than that, the really isn't a way without trading.

Hope I helped!

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Sea Mauville-Possible gift when you defeat Young Couple Lois & Hal in a rematch Destiny Knot
A possible gift from a fan in the Contest Hall after you beat Master Rank

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