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I accidentally defeated Kyogre in Alpha Sapphire and wondered if there is another way to catch it again. Will I be able to catch it again at the Cave of Origins if I defeated the Elite 4? Thanks.

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Yes

After you defeat the E4 you can rebattle it in the Cave of Origin
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I get to catch Kyogre. Thanks :D
No problem :D
I used a master ball to catch it!
Congratulations ^-^
:D