PokéBase - Pokémon Q&A
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I'm currently chaining for Luxio and I was wondering if it was possible for me to find a Level 34 rather than a 24 ("!" on the dexnav)

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You just have to raise the encounter level (the number of times you encountered luxio in your case). Then, you will have a higher chance of finding it.

Source 1: Experience
Source 2: http://bulbapedia.bulbagarden.net/wiki/DexNav

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