PokéBase - Pokémon Q&A
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Riolu

Cannot be found in Omega Ruby. Must be traded from XY.
In XY it can be found on Route 22 and the Friend Safari

Lucario

Cannot be found in Omega Ruby. Must be traded from XY
In XY you can obtain it In-Game with it holding a Lucarionite from Korrina at the Tower of Mastery

Lucarionite

Defeat Lissa and get through all Master Contests .

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As far as I know you can't find wild riolu in ORAS. However, you can get the Lucarioite in it. You have to beat the contest person (lilisa, lisa, I dunno) in master rank on all of them, then you get da mega stone. I've heard it's the hardest mega stone to get in the game.

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The Garchompite tho
Oh yeah
i feel like hardest is garchompite
Who needs Garchompite anyway? The standard is better.