PokéBase - Pokémon Q&A
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You encounter Drilbur and Boldore!
Drilbur used dig!
(Next turn)
You throw Pokeball at Boldore!
(Note: this example is not real, meaning in a game there might not be any double battle with a Drilbur and Boldore)
Would you
A: Throw the Pokeball, and have a chance of catching the Bordore?
B: It's impossible to aim with two Pokemon!

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"Option B", since it's true.
It is impossible it catch a Pokemon in double/triple battles if more than one Pokemon on the opponent's side is still alive - regardless of dig, fly, dive etc. Your trainer can't aim straight.

Source: http://bulbapedia.bulbagarden.net/wiki/Double_Battle

Hope I helped! :)

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