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I think I breifly remember him when Ash and his friends were on a train in an episode.

Edit: Or any of the seasons, really.

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Looker appeared in the following episodes (D/P):
-Frozen on Their Tracks!
-Gateway to Ruin!
-Unlocking the Red Chain of Events!
-The Battle Finale of Legends!

He also appears in the following B/W episodes:
-Team Plasma's Pokémon Power Plot!
-Team Plasma's Pokémon Manipulation!
-Ash and N: A Clash of Ideals!
-Team Plasma and the Awakening Ceremony!
-What Lies Beyond Truth and Ideals!
-Two unaired episodes

He was on the Ampharos Train, where he gave Team Rocket lunches, which made them start calling him the Boxed-Lunch Guy.
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Great answer, but just wondering, do you have the titles of the unaired episodes?
I dont think we know them
EDIT: Theyre called "Rocket-Dan vs Plasma-Dan"  parts one and two, i think.
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Looker made his debut appearance in the Diamond and Pearl series episode "Frozen on Their Tracks" he also appeared in 3 more episode of the DP series "Gateway to Ruin", "Unlocking the Red Cain of Events", and "The Battle Finale of Legend" He then reappeared in 3 episodes of the Best Wishes season during the Team Plasma Arc. "Team Plasmas Power Plot", "Team Plasmas Pokemon Manipulation", and "Ash and N: A Clash of Ideals". The unaried episodes of looker's appearance were titled Rocket-dan VS Plasma-dan! (Part 1), and Rocket-dan VS Plasma-dan! (Part 2)This is the source information:http://bulbapedia.bulbagarden.net/wiki/Looker#In_the_anime

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Yes, Looker is in the DP anime, as well as other episodes.
First appearance: Frozen on Their Tracks (D/P)
Second appearance: Gateway to Ruin (D/P)
Third appearance: Unlocking the Red Chain of Events (D/P)
Fourth appearance: Team Plasma's Pokémon Power Plot (B/W)
Fifth appearance: Team Plasma's Pokémon Manipulation (B/W
Sixth appearance: Ash and N: A Clash of Ideals (B/W)
Hope I helped!
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