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How do you get your Vivillion to have Sleep Powder?

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Move Relearner

Take Vivillion to a Move Relearner.
Dendemille Town in XY and and West of Fallabour Town in ORAS
Give him a Heart Scale and Vivillion will relearn Sleep Powder as Vivillion gets Sleep Powder at lv.1.

Vivillion's Moves Page

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You go to the move relearner, and with a heart scale, it should be able to be taught Sleep Powder.

Hope I helped!

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