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I'm playing Diamond and my Starly used Aerial Ace and it missed?
Help?

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Was the target using a two-turn move? That's the only case I can think of that could cause aerial ace to miss.
no.it used poision powder
Odd. Aerial ace never misses, unless the target is using Dig, Fly, etc.

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Aerial Ace inflicts damage and is unaffected by modifications to the accuracy stat and evasion stat. It will not hit a Pokémon during the semi-invulnerable turn of moves such as Dig, Fly, and Dive.

The only way Aerial Ace will miss is if a Pokémon is in the invulnerability stages of Dig, Fly etc. If this wasn't the case your game must have glitched.

Source - Bulbapedia

Hope I helped!

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It Definitely Glitched
That would explain it