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In ORAS, you can buy Timer Balls at the Rustboro City Pokemart. You can also get them as a gift when you defeat Pokemon Ranger Catherine or Pokemon Ranger Jackson in a rematch on Route 119.

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For some reason I can't get them at the rustboro city Pokemart does anyone know why
According to this, http://www.gamefaqs.com/boards/792673-pokemon-omega-ruby/70751525 you need to talk to the Devon employee to be able to get Timer Balls at the Rustboro City Pokemart.
Lol I was going to use them to catch post game legendary but so far I've got them all in quick balls