PokéBase - Pokémon Q&A
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When applying a Golden Bottle Cap or Silver Bottle Cap, will the Ev's be trained as well? or is that something that the individual trainer must accommodate ahead of time?

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To put it simply: Nope.

1 Answer

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No, Bottle Caps and Golden Bottle Caps will only increase the Pokemon's IVs.

As you said, the EVs must be accommodated otherwise. There are a multitude of ways to EV train Pokemon - these can range from defeating certain wild Pokemon or even in Poke Pelago. For a more detailed reading of EV training, check this Serebii page.

Source: experience

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