PokéBase - Pokémon Q&A
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Do you mean battling the totem of Sophocles trial, or battling Sophocles himself?

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On Route 2, you can encounter Growlithe, which evilve into Arcanine with a Fire Stone. If Kiawe's Trial is before Sophocles, you can get Salandit after beating Kiawe's Totem.

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If you chose Litten as your starter, you can use it for this trial.