PokéBase - Pokémon Q&A
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Merciless=When the enemy is poisoned, all damaging moves will be critical hits.
Lucky Chant=Every move the opponent uses cannot be a critical hit.

What occurs if a Merciless Toxapex uses an attack on a Pokémon who is poisoned, but used Lucky Chant? Which move/ability will override?

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What... What are you even asking?
@ Silvertail -- OP is asking what happens if a Maraenie/Toxipex with the ability Merciless attacks a target that is Poisoned (thus triggering Merciless) but is protected by Lucky Chant.

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Lucky Chant will override Merciless, so the critical hits will not be landed.

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