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If a Pokemon requires connecting a copy of Sun to a copy of Moon, that counts as "obtainable" (example: Necrozma). The only ones I know right now are island scan Pokemon and Zygarde. Please don't question my curiosity.

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What do you mean by connecting Sun and Moon? Necrozma doesn't need both games to appear.
Zygarde is in the Alola Pokédex (#205).
I thought it only appears after the player catches all the ultra beasts. Oh well.
Just the Ultra Beasts in the game, version-exclusives don't matter :)

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Island Scan Pokémon are the only Pokémon catchable in Sun/Moon that are not in the PokéDex. Here are all of them, plus their evolutions:

  • Totodile (+ Croconaw, Feraligatr)
  • Deino (+ Zweilous, Hydreigon)
  • Horsea (+ Seadra, Kingrda)
  • Klink (+ Klang, Klinklang)
  • Litwick (+ Lampent, Chandelure)
  • Cyndaquil (+ Quilava, Typhlosion)
  • Spheal (+ Sealeo, Walrein)
  • Luxio (+ Shinx, Luxray)
  • Honedge (+ Doublade, Aegislash)
  • Venipede (+ Whirlipede, Scolipede)
  • Bellsprout (+ Weepinbel, Victreebel)
  • Marill (+ Azurill, Azumarill)
  • Gothita (+ Gothorita, Gothitelle)
  • Swinub (+ Piloswine, Mamoswine)
  • Duosion (+ Solosis, Reuniclus)
  • Roselia (Budew, Roserade)
  • Staravia (+ Starly, Staraptor)
  • Vigoroth (+ Slakoth, Slaking)
  • Axew (+ Fraxure, Haxorus)
  • Rhyhorn (+ Rhydon, Rhyperior)
  • Conkeldurr (+ Timburr, Gurrdurr)
  • Togekiss (+ Togepi, Togetic)
  • Leavanny (+ Sewaddle, Swadloon)
  • Serperior (+ Snivy, Servine)
  • Samurott (+ Oshawott, Dewott)
  • Emboar (+ Tepig, Pignite)
  • Eelektross (+ Tynamo, Eelektrik)

That is all that I could find. Zygarde is in the Alola PokéDex (#205). You could maybe count the RotomDex, because you have one in-game but Rotom is not in the PokéDex data, but you can't use him in battle so it is debatable.

If you count the Sun/Moon Demo, you can also get a Greninja. Credit to MJC1011.

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you can also get greninja from the demo
Thanks, added it!
thx! (need 12 characters)