PokéBase - Pokémon Q&A
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I'd say "Whenever you feel like evolving it". If you feel like evolving it when it learns a decent enough move, then go for it. Don't let us tell you when to evolve your Exeggcute into Exeggutor. You evolve him/her when you think the time is right.

1 Answer

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The last good move it learns by level up is sleep powder, which it learns at level 37. Therefore, you should evolve it at level 37. I think it should know reflect, leech seed, confusion, and sleep powder when you evolve it.

What about TMs? Aren't they important? I feel they are. I have an Alolan Exeggutor that knows Dragon Hammer, Thief, Infestation, and Energy Ball.
Both Exeggcute and Exeggcutor had the same TMs during gen III FR/LG, albeit Exeggutor also has hyper beam.
What about teaching it Pshycic instead of Confusion?
You can teach it psychic whenever you want, including after it evolves. The four moves (reflect, leech seed, confusion, sleep powder) assume you don't like using TMs.