Meta Rate My Team PokéBase - Pokémon Q&A
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Yes it will. An OHKO move always has 30% accuracy, unless you use something that raises accuracy. Lock-on gives 100% accuracy to moves, so your OHKO move will always hit, provided you use Lock-on first.

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An OHKO move actually has 30+, adding one more percent for each level higher your pokemon is than the opponent.