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Regularly Charge Beam has a 70% chance to Raise the user's Special Attack by 1 Stage. (I know this sounds stupid but) Does it Become a 100% percent chance with Serene Grace? I was just curious because I want to Run this Charge Beam Meloetta-Aria set.

Meloetta @ Life Orb
Ability: Serene Grace
Evs: 252 SpA / 252 Spe / 6 Hp
Timid Nature (+Spe, -Atk)

Focus Blast
Hyper Voice
Charge Beam

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I thought that Charge Beam raised the Special Attack of the User's stats. If this is what you mean, you should probably rewrite your statement.
Oops you're right. I'll Edit now. Thanks for correcting me.

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Yes, Serene Grace and Charge Beam do interact in this way. You would effectively have a 140% chance to trigger the Special Attack boost, which the mechanics of the game would simply cut to a 100% chance.

No, you really shouldn't do this with Meloetta. It might work sometimes, but you are losing a lot of offensive ability with Charge Beam due to it's relatively speaking low BP at only 50, not to mention it's accuracy is 90% meaning you will occasionally miss.

If you were playing a more mixed defensive set you could use Calm Mind in order to setup both your Special Attack and your Special Defense, given Meloetta-Aria's stats naturally working in this direction (losing the Electric type attack altogether, however). However, the set you are proposing would work better with Thunderbolt, or if on a Rain team, Thunder (no accuracy check in Rain). Serene Grace would raise the Paralysis chance to 20% and 60%, respectively.

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Alright. Thanks for the feedback.