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Sort of like being able to find Life Orbs on wild Absol in ORAS

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There are a few that appear on wild Pokemon.

  • Grimer and Muk can hold Black Sludge
  • Munchlax and Snorlax will always be holding Leftovers
  • Makuhita can hold an Expert Belt
  • Bounsweet, Steenee, and Tsareena can hold a Grassy Seed
  • Togedemaru can hold an Electric Seed
  • Poliwhirl, Politoed, Poliwrath, Slowbro, Slowking, Hariyama, and Hawlucha can hold a King's Rock
  • Lombre, Leavannty, Pancham, and Pangoro can hold a Mental Herb
  • Comfey can hold a Misty Seed
  • Nuzleaf can hold a Power Herb
  • Scraggy, Goomy, and Sliggoo can hold a Shed Shell

Those are all the ones I could find. It does slightly depend on which items you consider "competitive" though. I mean, items can like the Absorb Bulb and the Cell Battery are also found on wild Pokemon, but I have never seen them used, so I don't really consider them a competitive item.

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