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It's all in the title.

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Jolteon. This answer is purely based on the fact that critical hits are based based on speed in generation 1, so you'll crit almost every other hit. Besides, it has a decent Special stat as well, that works well with its moves.

While Raichu is pretty good, it's not as fast, meaning that it gets lesser crits.

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Be careful of ground moves, since most will do significant damage to it