PokéBase - Pokémon Q&A
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On Pearl I mean.

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https://bulbapedia.bulbagarden.net/wiki/Cyndaquil_(Pok%C3%A9mon)
I didn't see any Generation 4 events when I scrolled down to events.

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The only Cyandiquil event here with a Cherish Ball is for Gen 6. The second one is for Gen 3 but it's in a Poké Ball so it doesn't matter. Those are the only Cyandiquil events to ever be made and they were all for Japan. Your answer is no.

I hope this helped!

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