You never told me what game you're playing, so I answered for every game where Serperior is obtainable during the main story.
BW and BW2: Grass pledge's base power is 50 in this game, so leaf tornado is stronger. If you have access to the other pledge moves, that means someone traded the other starters to you, and you should ask that person to take the starters back and give you a Kyogre instead. If you don't, then you should consider using Lilligant instead of Serperior because Lilligant has higher special attack and can learn sleep powder and quiver dance.
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SM: Grass pledge's base power is 80, so it's better than leaf tornado regardless of whether you have other pledge moves.